# Robust retrieval of material chemical states in X-ray microspectroscopy

arXiv: https://arxiv.org/abs/2308.04207 · HTML: https://mlsanity.com/paper/2308.04207/

## Key facts

- No citing papers in the map yet (data through 14 Oct 2026).
- Builds on 7 of its 48 references that are in the map.
- First posted on arXiv 8 Aug 2023.

## Builds on (most cited first, 7 of 7)

- [Beyond a Gaussian Denoiser: Residual Learning of Deep CNN for Image Denoising](https://mlsanity.com/paper/1608.03981/) (2016)
- [An Augmented Linear Mixing Model to Address Spectral Variability for Hyperspectral Unmixing](https://mlsanity.com/paper/1810.12000/) (2018)
- [Spectral Variability in Hyperspectral Data Unmixing: A Comprehensive Review](https://mlsanity.com/paper/2001.07307/) (2020)
- [Learning Deep Gradient Descent Optimization for Image Deconvolution](https://mlsanity.com/paper/1804.03368/) (2018)
- [A Plug-and-Play Priors Framework for Hyperspectral Unmixing](https://mlsanity.com/paper/2012.13074/) (2020)
- [Spectral Variability Aware Blind Hyperspectral Image Unmixing Based on Convex Geometry](https://mlsanity.com/paper/1904.03888/) (2019)
- [Integration of Physics-Based and Data-Driven Models for Hyperspectral Image Unmixing](https://mlsanity.com/paper/2206.05508/) (2022)

## Abstract (arXiv)

X-ray microspectroscopic techniques are essential for studying morphological and chemical changes in materials, providing high-resolution structural and spectroscopic information. However, its practical data analysis for reliably retrieving the chemical states remains a major obstacle to accelerating the fundamental understanding of materials in many research fields. In this work, we propose a novel data formulation model for X-ray microspectroscopy and develop a dedicated unmixing framework to solve this problem, which is robust to noise and spectral variability. Moreover, this framework is not limited to the analysis of two-state material chemistry, making it an effective alternative to conventional and widely-used methods. In addition, an alternative directional multiplier method with provable convergence is applied to obtain the solution efficiently. Our framework can accurately identify and characterize chemical states in complex and heterogeneous samples, even under challenging conditions such as low signal-to-noise ratios and overlapping spectral features. Extensive experimental results on simulated and real datasets demonstrate its effectiveness and reliability.